Di(2-pyridyl) carbonate promoted alkoxycarbonylation of amines: A convenient synthesis of functionalized carbamates

✍ Scribed by Arun K. Ghosh; Tien T. Duong; Sean P. McKee

• Book ID: 104225134
• Publisher: Elsevier Science
• Year: 1991
• Tongue: French
• Weight: 285 KB
• Volume: 32
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)92141-5

✦ Synopsis

The reaction of di(2-pyridyl) carbonate with a variety of alcohols including hindered secondary, tertiary and protected glycols afforded the corresponding mixed carbonate which was efficiently transformed into various carbamates in high yield under mild conditions.