𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Di-μ-pivalato-bis­[cis-diammineplatinum(II)] bis­(perchlorate) pivalic acid solvate

✍ Scribed by Sakai, Ken ;Ishigami, Eri ;Yokokawa, Kazuo ;Kajiwara, Takashi ;Ito, Tasuku

Publisher
International Union of Crystallography
Year
2003
Tongue
English
Weight
893 KB
Volume
59
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Bis{di-μ-isobutyrato-bis­[cis-diamminepl
Bis{di-μ-isobutyrato-bis­[cis-diammineplatinum(II)]} tetraperchlorate
✍ Sakai, Ken ;Ishigami, Eri 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 881 KB

The title compound, [Pt 2 ("-C 4 H 7 O 2 ) 2 (NH 3 ) 4 ] 2 (ClO 4 ) 4 , involves two independent diplatinum(II) units. For each unit, a pair of dimeric units located around an inversion center are associated with one another to give a tetranuclear Pt II 4 cation, in which the interdimer association

Di-μ-α-pyrrolidinonato-bis­[cis-diammine
Di-μ-α-pyrrolidinonato-bis­[cis-diammineplatinum(II)] sulfate monohydrate as a head-to-head isomer
✍ Sakai, Ken ;Sakai, Itsuki ;Draper, Neil D. ;Leznoff, Daniel B. 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 674 KB

In the title compound, [Pt II 2 (C 4 H 6 NO) 2 (NH 3 ) 4 ](SO 4 )ÁH 2 O, the intradimer Pt II ÐPt II distance is 2.9749 (11) A Ê , which is clearly shorter than the value of 3.029 (2) A Ê reported for a different salt of the same cation, viz. [Pt II 2 (C 4 H 6 NO) 2 (NH 3 ) 4 ] 2 (PF 6 ) 3 -(NO 3 )Á