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Di- or Trinuclear 3d–4f Schiff Base Complexes: The Role of Anions

✍ Scribed by Jean-Pierre Costes; Bruno Donnadieu; Ruxandra Gheorghe; Ghenadie Novitchi; Jean-Pierre Tuchagues; Laure Vendier


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
639 KB
Volume
2008
Category
Article
ISSN
1434-1948

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The 'H NMR spectra of acetate methyl signals of the titled three complexes in CD,OD change with time due to successive substitution of CD,OD for the coordinated water molecules. The first-order rate constants for the first methanol-d., substitution of the triruthenium(II1) and trirhodium(II1) comple