Di-d-fructose dianhydrides and related oligomers from thermal treatments of inulin and sucrose

✍ Scribed by Merilyn Manley-Harris; Geoffrey N. Richards

• Publisher: Elsevier Science
• Year: 1996
• Tongue: English
• Weight: 956 KB
• Volume: 287
• Category: Article
• ISSN: 0008-6215
• DOI: 10.1016/0008-6215(96)00071-7

✦ Synopsis

Thermal treatment of anhydrous, acidified sucrose or inulin yields caramels containing monosaccharides and oligomers, predominantly dianhydrides and higher oligomers derived by the addition of glycosyl residues to dianhydrides. Fourteen dianhydrides, most of which comprise two fructose moieties, have been identified by mass spectroscopy of the per-O-trimethylsilyl ethers. Thirteen of these dianhydrides have been isolated and characterized; five of the dianhydrides are novel compounds and one of these is a glucose-fructose dianhydride. The dianhydrides and related oligomers are thought to have a prebiotic effect by stimulating the proliferation of bifidobacteria in the large intestine.