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Di- and tri-nitro derivatives of 1-chloronaphthalene

✍ Scribed by H. F. Bassilios; A. Y. Salem; M. Shawky

Book ID
104586447
Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
345 KB
Volume
81
Category
Article
ISSN
0165-0513

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✦ Synopsis

Abstract

Nitration of 1‐chloronaphthalene with excess of fuming nitric acid at a relatively high temperature provided a mixture of 1‐chloro‐4,5‐ and 1‐chloro‐4,8‐dinitronaphthalenes. The same dinitro derivatives can be obtained by further nitration of 1‐chloro‐4‐nitronaphthalene. The nitration of 1‐chloro‐4,5‐dinitronaphthalene with either fuming nitric acid or mixed acids provides the known 1‐chloro‐2,4,5‐trinitronaphthalene, while that of 1‐chloro‐4,8‐dinitronaphthalene with fuming nitric acid yields a new trinitro derivative melting with decomposition at 270° which is confirmed as being 1‐chloro‐4,5,8‐trinitronaphthalene.

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