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Di-2-pyridyl sulfite. A new useful reagent for the preparation of N-sulfinylamines, nitriles, isocyanides, and carbodiimides under mild conditions

โœ Scribed by Sunggak Kim; Kyu Yang Yi


Book ID
118549885
Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
247 KB
Volume
27
Category
Article
ISSN
0040-4039

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Di-2-Pyridyl thionocarbonate. A new reag
โœ Sunggak Kim; Kyu Yang Yi ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 222 KB

Reaction of amines with di-2-pyridyl thionocarbonate affords the corresponding isothiocyanates at room temperature, while reaction of N,N'-disubstituted thioureas with di-2-pyridyl thionocarbonate in the presence of 4-dimethylaminopyridine as a catalyst affords the corresponding carbodiimides in hig