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DFT/NMR integrated approach: a valid support to the total synthesis of chiral molecules

✍ Scribed by Maria Giovanna Chini; Raffaele Riccio; Giuseppe Bifulco

Publisher: John Wiley and Sons
Year: 2008
Tongue: English
Weight: 272 KB
Volume: 46
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.2288

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✦ Synopsis

Abstract

The analysis of the configuration of kedarcidin chromophore and palau'amine through quantum chemical calculation of __J__s and chemical shifts suggests a fast and convenient quantum chemical approach that can be applied prior to proceeding to the total synthesis of complex natural compounds in order to avoid loss of time and resources employed in the total synthesis of wrong diastereoisomers. Copyright © 2008 John Wiley & Sons, Ltd.

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