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DFT Study on 3-Substituted Tetrahydropyran-2-yl Radicals

✍ Scribed by Kozmon, Stanislav; Tvaroška, Igor


Book ID
120025818
Publisher
UOCHB
Year
2006
Tongue
English
Weight
306 KB
Volume
71
Category
Article
ISSN
0010-0765

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## Abstract 4‐Substituted bicyclo [2.2.2] oct‐1‐yl radicals were generated by bromine atom abstraction from the corresponding 1‐bromobicyclo [2.2.2] octanes and observed in solution by EPR spectroscopy. A tendency towards lower __a__(H~β~) and __a__(H~γ~) values for inductively electron‐withdrawing