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DFT Study of the Palladium-Catalyzed Cyclopropanation Reaction

✍ Scribed by Bernardi, Fernando; Bottoni, Andrea; Miscione, Gian Pietro

Book ID
127154782
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
144 KB
Volume
20
Category
Article
ISSN
0276-7333

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Palladium-Catalyzed Cyclopropanation of
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✍ Michaelβ€…A. Emerzian; William Davenport; Jiangao Song; Jim Li; Ihsan Erden πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 212 KB

## Abstract magnified image Unsaturated bicyclic endoperoxides are efficiently cyclopropanated with excess diazomethane in the presence of catalytic palladium(II) acetate [Pd(OAc)~2~] in a stereoselective manner. This method represents a new peroxide‐preserving transformation. Whereas the unsatura