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DFT Studies on Gold-Catalyzed Cycloisomerization of 1,5-Enynes

✍ Scribed by Fan, Ting; Chen, Xihan; Sun, Jianwei; Lin, Zhenyang


Book ID
126210760
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
556 KB
Volume
31
Category
Article
ISSN
0276-7333

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Gold-catalyzed cycloisomerization reacti
✍ Jack Chang Hung Lee; Dennis G. Hall πŸ“‚ Article πŸ“… 2011 πŸ› Elsevier Science 🌐 French βš– 690 KB

Gold (I) complexes generated from a mixture of gold and silver salts were found to be highly reactive for the cycloisomerization reactions of boronated enynes. Both alkynyl pinacol boronates and alkenyl pinacol boronates were tolerated, affording products in moderate to high yields. Interestingly, t