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DFT and ab initio study on mechanism of olefin hydroalumination by XAlBui2 in the presence of Cp2ZrCl2 catalyst. III. Efficiency of transmetallation in Cp2ZrRCl–XAlBui2 system

✍ Scribed by Evgeniy Yu. Pankratyev; Sergey L. Khursan; Usein M. Dzhemilev

Book ID: 111966357
Publisher: Elsevier Science
Year: 2012
Tongue: English
Weight: 607 KB
Volume: 718
Category: Article
ISSN: 0022-328X
DOI: 10.1016/j.jorganchem.2012.07.027

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Kinetic model of olefin hydroalumination

Kinetic model of olefin hydroalumination by HAlBui2 and AlBui3 in the presence of Cp2ZrCl2 catalyst

✍ Lyudmila V. Parfenova; Alexandr V. Balaev; Irek M. Gubaidullin; Liya R. Abzalilo 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 213 KB

## Abstract The mechanism of α‐olefin hydroalumination by HAlBu^__i__^~2~, ClAlBu^__i__^~2~, and AlBu^__i__^~3~ in the presence of Cp~2~ZrCl~2~ catalyst has been studied. It was established that the key intermediate of the reaction is a bimetallic complex [Cp~2~ZrH~2~ · ClAlBu^__i__^~2~]~2~, which