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DFT-aided interpretation of the Raman spectra of the polymorphic forms of Y2Si2O7

✍ Scribed by Reinhard Kaindl; Daniel M. Többens; Volker Kahlenberg


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
158 KB
Volume
42
Category
Article
ISSN
0377-0486

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📜 SIMILAR VOLUMES


The thermochemical properties of Y2Si2O7
✍ E.H.P. Cordfunke; A.S. Booij; R.R. van der Laan 📂 Article 📅 1998 🏛 Elsevier Science 🌐 English ⚖ 143 KB

The enthalpy increments of Y Si O and Dy Si O have been measured by drop-calorimetry 2 2 7 2 2 7 Ž . Ž . from T s 516.7 to 928.4 K, and T s 516.7 to 918.2 K, respectively. The standard molar enthalpy of formation of monoclinic Y Si O has been deduced from its enthalpy of solution 2 2 7 . y3 . y3 T Ž

The standard molar enthalpies of formati
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The standard molar enthalpies of solution of cerium and lanthanum silicates (b-Ce2Si2O7 and b-La2Si2O7) in (6.20 mol•dm -3 HCl + 0.147 mol•dm -3 HF) (aq) were measured. From these values the standard molar enthalpies of formation have been deduced: DfH°m(Ce2Si2O7, cr, b, 298.15 K) = -(3807.6 2 4.5)

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