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Dewar Benzene and Some of its Derivatives. A photoelectron spectroscopic analysis [1]

✍ Scribed by Gerhard Bieri; Edgar Heilbronner; Tsunetoshi Kobayashi; Andreas Schmelzer; Melvin J. Goldstein; Ronald S. Leight; Mark S. Lipton

Publisher: John Wiley and Sons
Year: 1976
Tongue: German
Weight: 934 KB
Volume: 59
Category: Article
ISSN: 0018-019X
DOI: 10.1002/hlca.19760590805

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The near degeneracy of the two lowest ionization energies of Dewar benzene can be understood in terms of closely competitive ‘through‐bond’ and ‘through‐space’ interaction. Empirical, semiempirical, and open‐shell ab initio procedures converge to require mutually consistent symmetry assignments.

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