Devolatilization of large coal particles at high pressure
β Scribed by Craig N. Eatough; L. Douglas Smoot
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 697 KB
- Volume
- 75
- Category
- Article
- ISSN
- 0016-2361
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β¦ Synopsis
Devolatilization times of large (0.1 and 0.2 g) Utah hvBb and North Dakota lignite coal particles, in the range 15-30s were measured in air at 101 and 507 kPa, at air temperatures of 900 and 1200K in a convective flow reactor. Visual observations indicated infrequent heterogeneous ignition of the lignite prior to devolatilization and occasional explosion of bituminous coal particles during devolatilization. Devolatilization times were correlated with temperature, pressure and particle size. Power-law exponents for tests at 101 kPa and 900K were determined to be 2.5 for Utah hvBb coal and 2.2 for North Dakota lignite. At 507 kPa and 900 K, exponents decreased to 1.6 for both Utah and North Dakota coals. At 101 kPa and 1200 K, exponents were 1.9 for Utah coal and 1.6 for North Dakota lignite.
π SIMILAR VOLUMES
Analysis of devolatilization of predried large coal particles in fluidized beds requires consideration of both the chemical kinetics of coal decomposition and transport processes. Models available either assume the devolatilization particle to be isothermal (whereas it may be shown that, in general,
Here, reflt'x'ted shock temperatures were calcu-lal~ by assuming that tmndational, rotational and vii~rational freedoms of all species were completely relaxed. However, vibrational relaxation of nitrogen is comparable to the induction peric, d in the present experimental conditions -~. Another calcu