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Developments of Asymmetric Synthesis Mediated by Chiral Sulfur Reagents

✍ Scribed by Blot, Virginie; Brièr, Jean-François; Davoust, Marion; Minière, Stéphanie; Reboul, Vincent; Metzner, Patrick

Book ID
121350726
Publisher
Taylor and Francis Group
Year
2005
Tongue
English
Weight
185 KB
Volume
180
Category
Article
ISSN
1042-6507

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Asymmetric arene-alkene cyclizations med
Asymmetric arene-alkene cyclizations mediated by a chiral organoselenium reagent
✍ Robert Déziel; Eric Malenfant; Carl Thibault 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 227 KB

Asymmetric arene-alkene cyclization reactions mediated by a chiral electrophilic organoselenium reagent afforded substituted carbocyclic derivatives with high diastereoselectivities. It was also found that [3-methoxyselenides are good precursors of seleniranium ions when treated with strong acids.