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Development, Scope, and Mechanism of the Palladium-Catalyzed Intramolecular Hydroalkylation of 3-Butenyl β-Diketones.

✍ Scribed by Hua Qian; Tao Pei; Ross A. Widenhoefer

Publisher
John Wiley and Sons
Year
2005
Weight
22 KB
Volume
36
Category
Article
ISSN
0931-7597

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✦ Synopsis

2005 Cyclohexane derivatives Q 0040 Development, Scope, and Mechanism of the Palladium-Catalyzed Intramolecular Hydroalkylation of 3-Butenyl β-Diketones. -A detailed account on previously published studies is presented. The title reaction provides the first examples for transition metal-catalyzed addition of an active methylene group to an unactivated olefin.

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✍ Yuanjing Xiao; Junliang Zhang 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 360 KB 👁 2 views

## Abstract magnified image Described herein is the development of a palladium(II)‐catalyzed two‐ or three‐component reaction of 2‐(1‐alkynyl)‐2‐alken‐1‐ones with nucleophiles and allylic chlorides. Various types of nucleophiles such as __O‐__, __N‐__, __C__‐based nucleophiles and olefin‐tethered