Development of the “binary interaction” theory for entangled polydisperse linear polymers
✍ Scribed by D. W. Mead
- Publisher
- Springer-Verlag
- Year
- 2006
- Tongue
- English
- Weight
- 522 KB
- Volume
- 46
- Category
- Article
- ISSN
- 0035-4511
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We present an extension of the Rouse-CCR tube model for linear entangled polymers, by incorporating interchain repulsive excluded-volume interactions, to interpret extensional viscosity data of narrow molecular weight distribution polystyrene melts in strong extensional flows. The expression for the
## Abstract For a binary mixture of polydisperse polymers with strong interactions, the free energy, the equation of state, the chemical potentials and the spinodal are formulated on the basis of the lattice fluid model. Further, the spinodal curves for the system with strong interactions are simul