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Development of Reactions of Silacyclopropanes as New Methods for Stereoselective Organic Synthesis

✍ Scribed by Franz, Annaliese K.; Woerpel, K. A.


Book ID
120444393
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
443 KB
Volume
33
Category
Article
ISSN
0001-4842

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Stereoselective Synthesis of 4,5-Diethyl
✍ Rafael MartΓ­nez; Hugoβ€…A. JimΓ©nez-VΓ‘zquez; Alicia Reyes; JoaquΓ­n Tamariz πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 German βš– 339 KB πŸ‘ 2 views

The N-substituted isomeric (4Z,5Z)-and (4E,5Z)-4,5-diethylideneoxazolidin-2-ones 5 and 6 were synthesized, the latter being favored during the one-step process from the a-diketone 1c and different isocyanates. The steric interaction between the N-substituent and the Me group attached to the exocycli