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Development of high performance catalysts for the production of vinyl acetate monomer

โœ Scribed by Roman Renneke; ShaRee McIntosh; Venu Arunajatesan; Marisa Cruz; Baoshu Chen; Thomas Tacke; Hans Lansink-Rotgerink; Andreas Geisselmann; Ralf Mayer; Ralf Hausmann; Peter Schinke; Uwe Rodemerck; Mariana Stoyanova

Book ID
106548024
Publisher
Springer
Year
2006
Tongue
English
Weight
412 KB
Volume
38
Category
Article
ISSN
1022-5528

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The synthesis of a new palladacycle cata
The synthesis of a new palladacycle catalyst. Development of a high performance catalyst for Heck reactions
โœ Futoshi Miyazaki; Kentaro Yamaguchi; Masakatsu Shibasaki ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 298 KB

The new palladacycle catalyst 5 was synthesized, and this Pd catalyst showed high catalytic activity with turnover numbers of up to 8 900 000 (mol product per mol Pd) and turnover frequencies of up to 400 000 (mol product per mol Pd per h) in the coupling of aryl halides with olefins. This is the hi