Development of expanded and core kinetic models for the gas phase formation of dioxins from chlorinated phenols
โ Scribed by L. Khachatryan; R. Asatryan; Barry Dellinger
- Book ID
- 117249714
- Publisher
- Elsevier Science
- Year
- 2003
- Tongue
- English
- Weight
- 204 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0045-6535
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๐ SIMILAR VOLUMES
The homogeneous, gas-phase formation of polychlorinated dibenzo-p-dioxins (PCDD) and polybrominated dibenzo-p-dioxins (PBDD) has been observed from the high-temperature thermal decomposition of 2,4,6trichlorophenol (2,4,6-TCP) and 2,4,6-tribromophenol (2,4,6-TBP), respectively. Experiments were cond
## Abstract HCl elimination from chloroform is shown to be the lowest energy channel for initiation in the thermal conversion of chloroform to CCl~4~, with chlorine gas in the temperature range of 573โ635 K. Literature data on this reaction is surveyed and we further estimate its kinetic parameters