Development of Cyclic Propagation Kinetics for Modeling the Nitroxide-mediated Radical Copolymerization of Styrene-Divinylbenzene
✍ Scribed by Aguiar, Leandro G.; Gonçalves, Miguel A. D.; Pinto, Virgínia D.; Dias, Rolando C. S.; Costa, Mário Rui P. F. N.; Giudici, Reinaldo
- Book ID
- 121017804
- Publisher
- John Wiley and Sons
- Year
- 2013
- Tongue
- English
- Weight
- 885 KB
- Volume
- 8
- Category
- Article
- ISSN
- 1862-832X
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## Abstract Recently experimental data on the free radical copolymerization of styrene and methyl methacrylate in bulk were shown to obey penultimate model kinetics. These data were now reevaluated with respect to copolymerization parameters by means of a simultaneous fit of the penultimate model b
Nitroxide-mediated radical copolymerization of styrene (99 mol%)/divinylbenzene (1 mol%) employing the nitroxide 2,2,6,6-tetramethylpiperidinyl-1-oxy (TEMPO) in aqueous miniemulsion using sodium dodecylbenzenesulfonate as surfactant has been carried out at 125 C. At a given styrene conversion, the d