Development of a Scaleable Synthesis for 1,2-Bis(2-aminophenylthio)ethane (APO-Link) Used in the Production of Bismaleimide Resin
✍ Scribed by Densmore, Crystal G.; Wheeler, Hilary; Cohenour, Rebecca; Robison, Thomas W.; Hasam, Dawud; Cordova, Blossom J.; Stark, Peter C.; Fuller, Edward N.; Cook, Charles J.; Weber, Holly A.
- Book ID
- 127188583
- Publisher
- American Chemical Society
- Year
- 2007
- Tongue
- English
- Weight
- 156 KB
- Volume
- 11
- Category
- Article
- ISSN
- 1083-6160
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S,S)-1,2-Bis(boranato(tert-butyl)phosphino)ethane has been synthesized efficiently and in excellent enantioselectivity. This secondary diphosphine serves as the starting material for an elegant preparation of (R,R)-1,2-bis(boranato(tertbutyl)methylphosphino)ethane, known as (R,R)-t-Bu-BisP\*-borane.
## Abstract A rapid and sensitive liquid chromatography/electrospray ionization tandem mass spectrometric (LC/ESI‐MS/MS) method has been developed to determine 1, 2‐[bis(1,2‐benzisoselenazolone‐3(2H)‐ketone)]‐ethane (BBSKE), a novel antineoplastic agent, in rat plasma. The analytes were separated o