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Development of a One-Pot in Situ Synthesis of Poly(dichlorophosphazene) from PCl 3

โœ Scribed by Wang, Bin


Book ID
121866753
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
67 KB
Volume
38
Category
Article
ISSN
0024-9297

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Unexpected reactivity between aromatic n
โœ Rodolphe Abdayem; Graziano Baccolini; Carla Boga; Magda Monari; Simona Selva ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 175 KB

The reaction between 4-nitroalkoxybenzenes 7 and PCl 3 /AlCl 3 , when carried out in appropriate molar ratio, gives a prevalent formation of diazenes 8 and 2,7-dialkoxyphenazines 9 with their new chlorinated derivatives 10-13. These compounds are obtained, in satisfactory yield, in a one-pot procedu