A flexible polymer having propargyl moieties (2) was prepared by the cationic polymerization of vinyl monomer (1) derived from 4-hydroxybutyl vinyl ether and propargyl bromide. In the presence of the polymer, the catalytic activity of H PtCl towards the hydrosilylation of triethylsilane and trimethy
Development and Application of Latent Catalysts for Hydrosilylation System. 1. Control of Activity of Platinum Catalyst by Isocyanide
β Scribed by Kishi, Katsuhiko; Ishimaru, Taizo; Ozono, Masayoshi; Tomita, Ikuyoshi; Endo, Takeshi
- Book ID
- 126820013
- Publisher
- American Chemical Society
- Year
- 1998
- Tongue
- English
- Weight
- 89 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0024-9297
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A new thermal latent hydrosilylation catalyst on the basis of H 2 PtCl 6 and polystyrene derivatives having propargyl moieties is described. The polystyrene derivatives having various propargyl moieties were obtained by the reaction of propargyl alcohols with poly(p-chloromethylstyrene) or its copol
A new thermal-latent hydrosilylation catalyst consisting of H 2 PtCl 6 and polymers bearing amine moieties is described. In the presence of aminated polymers, the catalytic activity of H 2 PtCl 6 was suppressed remarkably in the model reaction of triethylsilane with trimethylvinylsilane, whose effec