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Deuteron NMR spectroscopy as a probe of the stereochemistry of biosynthetic reactions: the biosynthesis of lupanine and sparteine

✍ Scribed by Golebiewski, W. Marek; Spenser, Ian D.


Book ID
126226785
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
298 KB
Volume
106
Category
Article
ISSN
0002-7863

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The stereochemistry of 1,Z-disubstituted fluoroethylenes, of general formula RCH,CH=CFR', has been ascertained from the different magnitudes of the upfield shift effect promoted by fluorine on the "C NMR absorptions of the underlined y-carbon of the fluorinated analogue in comparison with those of t