The reaction route of the hydrogen electrode reaction on Ni, Rh, Au, and Pt at the reversible potential was investigated through the exchange reaction between deuterium and light water. Various reaction routes involving hydrogen adatom H(a) and adsorbed hydrogen molecule-ion H;(a) as the reaction in
Deuterium Tracer Studies on the Elimination Reactions of Norbornyl Tosylate and Bromide. XI
β Scribed by Kwart, H.; Takeshita, T.; Nyce, J. L.
- Book ID
- 126440363
- Publisher
- American Chemical Society
- Year
- 1964
- Tongue
- English
- Weight
- 772 KB
- Volume
- 86
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
The exchange reaction bctwccn deuterium gas and light water was conducted with Ni, Rh, and Pt catalyst. Through analysis of isotopic composition of the gaseous hydrogen during the exchange reaction, the exchange rates of the individual steps, H2 s 2H(a) and H(a) + B Z+ H+B + r, of the hydrogen elect
The stoichiometric number of the hydrogen electrode reaction on Rh, Ni, Pt, Au, Ag, and Ir was determined by means of deuterium tracer at the reversible potential. It is shown that, along with the change of the rate-determining step in the reaction route, H, $2H(a) followed by H(a) + B z$ H+B + e, w