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Deuterium-NMR investigation of plant sterol effects on soybean phosphatidylcholine acyl chain ordering

✍ Scribed by Marie-Anne Krajewski-Bertrand; Alain Milon; Marie-Andrée Hartmann


Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
395 KB
Volume
63
Category
Article
ISSN
0009-3084

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✦ Synopsis


Various plant sterois have been tested for their ability to order soybean phosphatidylcholine bilayers as monitored by 2H-NMR spectroscopy. Sitosterol and 24~-methylpollinastanol, a 9B, 19-cyclopropylsterol, appear to be the most effective sterols. The presence of either a trans-oriented double bond at C-22 in the C-24 alkylated sterol side chain or a A 8(9) in the tetracyclic ring system is shown to reduce significantly the ordering efficiency of the sterol molecule.