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Deuterium labelled borocryptands: synthesis, structural analysis and binding studies

✍ Scribed by Ernest Graf; Mir Wais Hosseini; André De Cian; Jean Fischer

Book ID
104259226
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
263 KB
Volume
39
Category
Article
ISSN
0040-4039

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✦ Synopsis

High yield syntheses of two new deuterium labelled compound 2 and 3 based on the [22] macrocyclic backbone bearing two catechol units was achieved. The solid state structure of the tetradeuterated compour d 3 was elucidated by X-ray diffraction methods. The binding ability of 2 and 3 towards both boron and alkaline metal cations was established in solution by 1H-, 2D-and 11B.NM R spectroscopy.

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