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Deuterium isotope effects on the rates of thermal decomposition of 2,2',4,4',6,6'-hexanitrostilbene in the condensed phase

✍ Scribed by Kony, Michael; Dagley, Ian J.; Whelan, Daniel J.

Book ID
120585947
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
800 KB
Volume
96
Category
Article
ISSN
0022-3654

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Studies on the Synthesis of 2,2′,4,4′,6,
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## Abstract First‐order rate constants for formation of cyclohexanone and 2‐cyclohexen‐1‐ol from 1,2‐epoxycyclohexane and 1,2‐epoxycyclohexane‐3,3,6,6‐__d__~4~ have been determined over the temperature range of 677–746°K. The observed kinetic isotope effects are used in an attempt to determine the