Deuterium Isotope Effects on the Protolytic Dissociation of Organic Acids in Electronically Excited States
β Scribed by Wehry, E. L.; Rogers, L. B.
- Book ID
- 126286843
- Publisher
- American Chemical Society
- Year
- 1966
- Tongue
- English
- Weight
- 450 KB
- Volume
- 88
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
A dissociation process of p-naphtha1 in the excited state has been investigated by measuring the fluorescence decay and the time-resolved spectra. A significant isotope effect on the rate of dissociation has been observed, and the activation energies for the proton transfer are determined. The exper
llc kmctlcs of the dlsFocl.ltlon rcnctmn of cdrbazolc in the e\cltcd stdtl: has been mve\tit;ated by measurinu ihe fluur-~SL'C~LC I~fctm~ m ddute .Ilkaline 1120 und D20 solutions. A norm,11 Isotope effca 11.1s been observed on the d&soc:ation reactlon rate, but the dltfcrencc of the actlvatlon encrg
The static and transient fluorescence spectroscopy of 3-hydroxyflavone, 3HF, has been investigated as a function of deuteration of the 3-hydroxy group and the solvent. Small H/D isotope effects are observed for at least two of the simple rate constants for the excited-state dynamics. The isotope eff