Deuterium isotope effects in the 1H, 13C, and 29Si NMR spectra of phenylsilanes
✍ Scribed by Edvards Liepiņš; Vladimir Gevorgyan; Edmunds Lukevics
- Book ID
- 107798321
- Publisher
- Elsevier Science
- Year
- 1989
- Weight
- 184 KB
- Volume
- 85
- Category
- Article
- ISSN
- 0022-2364
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Chemical shift and scalar coupling constant data have been obtained for the 'H, -C and "Si nuclei in dyl, methallyl, cis-and trans-croty1, cis-2-methyI-2-butenyl and 3-methyl-2-butenyl derivatives of trimethylsilane.
A detailed analysis of the -C NMR spectra of trans-stilbene and ten deuteriated trans-stilbenes has been undertaken. Some unusual deuterium isotope effects on carbon-hydrogen spin-spin coupling constants could not be explained by the ordinary primary and secondary isotope effects. The positive and n
In this and subsequent papers the deuterium isotope effect is defined as h(D,H)=S(D)-h(H) following the convention used in referencing chemical shifts [ 101.