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Deuterium Isotope Effect on the Excited-State Photophysics of Hypocrellin: Evidence for Proton or Hydrogen Atom Transfer

โœ Scribed by Das, K.; English, D. S.; Petrich, J. W.


Book ID
126935849
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
195 KB
Volume
101
Category
Article
ISSN
1089-5639

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Hydrogen/deuterium isotope effects on th
โœ A.J.G. Strandjord; P.F. Barbara ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 631 KB

The static and transient fluorescence spectroscopy of 3-hydroxyflavone, 3HF, has been investigated as a function of deuteration of the 3-hydroxy group and the solvent. Small H/D isotope effects are observed for at least two of the simple rate constants for the excited-state dynamics. The isotope eff