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Deuterium isotope effect in the T1 → S0 radiationless transition of propynal in the gas phase

✍ Scribed by U. Bruhlmann; P. Russegger; J.Robert Huber

Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
691 KB
Volume
75
Category
Article
ISSN
0009-2614

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The kinetics of the gas phase intramolecular elimination of isobutene from 2-d1-triisobutylaluminum and the deuterium isotope effect in reactions involving cyclic transition states
✍ Kurt W. Egger 📂 Article 📅 1969 🏛 John Wiley and Sons 🌐 English ⚖ 654 KB

The intramolecular elimination of isobutene from 2-d,-triisobutylaluminum has been studied in the gas phase for temperatures ranging between 102.4 and 184.6'C. The reaction is apparently homogeneous and obeys the first order rate law, yielding the following Arrhenius relationship: log kelim (sec-')