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Deuterium Isotope and Solvent Effects on the Kinetics of the Keto-enol Interconversion of 2-Acetylcyclohexanone

✍ Scribed by Riley, T.; Long, F. A.

Book ID
127064682
Publisher
American Chemical Society
Year
1962
Tongue
English
Weight
643 KB
Volume
84
Category
Article
ISSN
0002-7863

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3-Pentanone-2,2-d 2 was subjected to enolization by lithium diisopropylamide (LDA), lithium N-isopropyl(trimethylsilyl)amide (LITA), and lithium hexamethyldisilazide (LHMDS). Internal deuterium kinetic isotope effects were measured by 1 H-NMR analysis of the corresponding trimethylsilyl enol ethers