✦ LIBER ✦

Deuteration effects on the phosphorescence of aromatic hydrocarbons

✍ Scribed by J.B. Birks; T.D.S. Hamilton; J. Najbar

Publisher: Elsevier Science
Year: 1976
Tongue: English
Weight: 363 KB
Volume: 39
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(76)80300-4

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✦ Synopsis

bbservations of the phosphorescence decay of isotopic mixtures of naphthalene-ha and d &hD p enanthrene-h 10 and -dlo, and chrysene-h Iz and d12, in ethanol solutions at 77 K are anaIyscd to determine !he ratio .k~/k~ of the tripIet radiative rate parameters of the perprotonated and perdeuterated compounds. The ratio is 1.20 (eO.07) for naphthalene, 1.39 00.06) for phenanthrene, and 0.98 (kO.04) for chrysene.

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