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Deuteration effect on the spin dynamics of the photo-excited triplet state of pentacene in p-terphenyl crystals

✍ Scribed by Jui-Lin Ong; David J. Sloop; Tien-Sung Lin


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
490 KB
Volume
241
Category
Article
ISSN
0009-2614

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✦ Synopsis


The kinetic parameters of the photo-excited triplet state of pentacene in p-terphenyl crystals have been calculated from the electron spin echo (ESE) decay curves in the temperature range of 5-300 K. The results suggest the calculated decay parameters depend strongly on guest deuteration, especially from the long-axis T x spin substate which can be explained in terms of the isotope effect on the non-radiative transitions arising mainly from the Franck-Condon factor. The relative populations of the triplet sublevels and spin-lattice relaxation show little or no dependence on the deuteration of the pentacene molecule.


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