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Determining the Number of Resonance Structures in Concealed Non-Kekuléan Benzenoid Hydrocarbons

✍ Scribed by Dias, J.R.; Cash, G.C.


Book ID
126267156
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
81 KB
Volume
41
Category
Article
ISSN
0095-2338

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This Text Is An Attempt To Outline The Basic Facts Concerning Kekul€ Structures In Benzenoid Hydrocarbons: Their History, Applica Tions And Especially Enumeration. We Further Point Out The Numerous And Often Quite Remarkable Connections Between This Topic And Various Parts Of Combinatorics And Discr

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The linear dependence, previously claimed, of the total -rr-electron energy (E~) of isomeric benzenoid hydrocarbons on the number of Kekul6 structures (K) is found to be a satisfactory approximation only for benzenoids having eight or fewer six-membered rings (h ~< 8), and is violated if h >1 9. For