Abstract
A micellar electrokinetic capillary chromatographic (MEKC) procedure has been developed for the separation and determination of dioxouranium (VI), iron(III), copper(II), and nickel(II) using bis(salicylaldehyde)propylenediimine (H~2~SA~2~Pn) as chelating reagent with a total run time of <3 min. Sodium dodecyl sulphate (SDS) was used as micellar medium at pH 8.1 with sodium tetraborate buffer (0.1 M). Uncoated fused silica capillary with effective length 38.8 cmΓ75 ΞΌm id was used with an applied voltage of 30 kV and photoβdiode array detection at 228 nm. Linear calibrations were established within 0.045β1000 ΞΌg/mL of each element with detection limit within 15β122 ng/mL. The method was applied to the analysis of spring water and rock samples. The presence of uranium in rock and spring water samples was established within 1.58β1739.3 ΞΌg/g and 0.047β0.712 ΞΌg/mL with relative standard deviation within 0.9β2.1% and 1.3β2.6% respectively. Uranium ore and water samples were also assayed by the standard addition technique. Recovery of uranium was >98% with RSD up to 2.7%. Copper, nickel, and iron in their combined matrix were concurrently determined within RSD 0.6β3.6% (n = 5) and the results obtained were compared with those of flame AAS.