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Determination of triphenyltin hydroxide derivatives by capillary GC and tin-selective FPD

✍ Scribed by Wright, B. W. ;Lee, M. L. ;Booth, G. M.

Publisher
John Wiley and Sons
Year
1979
Tongue
English
Weight
207 KB
Volume
2
Category
Article
ISSN
0935-6304

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✦ Synopsis

Abstract

A new method for the determination of triphenyltin hydroxide using capillary column gas chromatography with a tin‐selective flame photometric detector has been developed. Triphenyltin hydroxide and its potential metabolites are converted to methyl derivatives and separated on glass capillary columns coated with OV‐101. Derivatization of triphenyltin hydroxide, triphenyltin chloride, diphenyltin dichloride, phenyltin trichloride, and bis‐triphenyltin oxide is nearly quantitative with a minimum of redistribution products. The selectivity of the flame photometric detector is cearly demonstrated by the comparison of chromatographic profiles obtained from using both the flame photometric and flame ionization detectors.

The use of this chromatographic system in the analysis of triphenyltin hydroxide in a fortified water sample demonstrates the potential use of this system in organotin residue chemistry.

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## Abstract Capillary GC on permethyl α‐, β‐, and γ‐cyclodextrins has been applied to separate and quantify the enantiomers of some 2,3‐iso‐propylidene‐1,2,3‐cyclohexanetriol derivatives. Quantitative CGC data are compared to those obtained with chiral shift ^1^H NMR.