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Determination of trans double bonds in polyunsaturated fatty acid methyl esters from their electron impact mass spectra

✍ Scribed by Svein Are Mjøs; Jan Pettersen


Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
225 KB
Volume
105
Category
Article
ISSN
1438-7697

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Trimethylsilylated methyl esters of octadecadienoic, eicosadienoic, and octadecatrienoic acids, after stereospecific oxidation, were investigated by combined gas chromatography-chemical ionization mass spectrometry. Molecular weight could be determined by the ions at m/e(M -1)' and (M + 73)+ and the