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Determination of the transition probability (reciprocal of lifetime) of excited atoms and ions from spectroanalytical data and the importance of lifetime values in spectrochemistry

✍ Scribed by N.W.H. Addink

Publisher: Elsevier Science
Year: 1959
Weight: 627 KB
Volume: 15
Category: Article
ISSN: 0371-1951
DOI: 10.1016/s0371-1951(59)80326-x

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✦ Synopsis

The purpose of this investigation was to discover why some of the spectral lines used in our method of spectrum analysis do not meet the requirements of reproducibility. While studying the origin of these lines it was found necessary to calculate their transition probability (reciprocal of lifetime), which proved that a relatively long lifetime is responsible for emission disturbances (collisions of the second kind).

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