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Determination of the transfer constant with bromotrifluoromethane in the polymerization of styrene

✍ Scribed by Thomson, R. A. M. ;Walters, I. R. ;King, J. R.

Publisher
Wiley (John Wiley & Sons)
Year
1972
Tongue
English
Weight
217 KB
Volume
10
Category
Article
ISSN
0449-2986

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Determination of transfer constants of non-ionic thiolended surfactants (transurfs) in styrene free-radical polymerizations
✍ FrΓ©dΓ©ric Vidal; Robert G. Gilbert πŸ“‚ Article πŸ“… 1996 πŸ› John Wiley and Sons 🌐 English βš– 260 KB

## Abstract The transfer constants of 1‐dodecanethiol and non‐ionic thiol‐ended surfactants (transurfs) have been determined for the bulk polymerization of styrene at 70Β°C; these values are 19 for l‐dodecanethiol and 19 and 14 for the transurfs with 17 and 90 ethylene oxide units, respectively. Tra