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Determination of the Tolman cone angle from crystallographic parameters and a statistical analysis using the crystallographic data base

✍ Scribed by Thomas E. Müller; D. Michael P. Mingos


Publisher
Springer
Year
1995
Tongue
English
Weight
625 KB
Volume
20
Category
Article
ISSN
0340-4285

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✦ Synopsis


A new method of evaluating the Tolman cone angle from X-ray structural data available from the Cambridge Crystallographic Data Base has been developed and a statistical analysis of the cone angles of the phosphines PPh3, PMe2Ph, PMePh 2, PMe 3, PEt 3 and PCy 3 (Cy = cyclohexyl) in transition metal complexes has been completed.


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