Determination of the Tolman cone angle from crystallographic parameters and a statistical analysis using the crystallographic data base
✍ Scribed by Thomas E. Müller; D. Michael P. Mingos
- Publisher
- Springer
- Year
- 1995
- Tongue
- English
- Weight
- 625 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0340-4285
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✦ Synopsis
A new method of evaluating the Tolman cone angle from X-ray structural data available from the Cambridge Crystallographic Data Base has been developed and a statistical analysis of the cone angles of the phosphines PPh3, PMe2Ph, PMePh 2, PMe 3, PEt 3 and PCy 3 (Cy = cyclohexyl) in transition metal complexes has been completed.
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