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Determination of the tacticity and analysis of the pH titration of poly(acrylic acid) by proton and carbon-13 NMR

โœ Scribed by Chang, Chen; Muccio, Donald D.; St. Pierre, Thomas


Book ID
118745894
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
524 KB
Volume
18
Category
Article
ISSN
0024-9297

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Sequence distribution of atactic poly(phenylvinylketone) (PPVK) has been determined by [13C]-[IH]NMR spectroscopy. Quantitative analysis of the carbonyl pattern allows resolution into pentads with intensities fitting a first order Markov process. The carbonyl pattern of highly isotactic PPVK, initia