Polymers 1 of the title monomer, prepared using well-defined molybdenum carbene complexes as catalysts, have been hydrogenated and the structures of the resultant polymers 2 examined by I3C NMR spectroscopy. The hydrogenated polymer made from the all-cis isotactic polymer of (+)-monomer showed a sin
Determination of the tacticities of ring-opened metathesis polymers of symmetrical 5,6-disubstituted derivatives of norbornene and norbornadiene from the 13C NMR spectra of their hydrogenated derivatives
✍ Scribed by V Amir-Ebrahimi; D.A.K Corry; J.G Hamilton; J.J Rooney
- Book ID
- 104424000
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- English
- Weight
- 188 KB
- Volume
- 133
- Category
- Article
- ISSN
- 1381-1169
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📜 SIMILAR VOLUMES
13C NMR spectra of the three title polymers have been determined for polymers of different tacticities. Assignments to the various possible HWHT/TT and m/r dyad structures were made. These were facilitated by the use of optically active monomers in the case of 1 and 3. In the precursor polymers the
## Abstract The ^1^H and ^13^C NMR spectra of __trans__‐ and __cis__‐__tert__‐butyl 2‐methoxy‐5,6‐dihydro‐2__H__‐pyran‐6‐carboxylates (1 and 2) and 6,6′‐disubstituted 2‐methoxy‐5,6‐dihydro‐2__H__‐pyrans (3‐7) have been recorded. HH and CH coupling constants are discussed in terms of the ^1^H~6~⇄^6^