Determination of the rα structure corrected for correlated deformation and of the bond contributions to the degree of order of 1,3-butadiene by NMR of the partially oriented molecule
✍ Scribed by R. Wasser; P. Diehl
- Publisher
- Springer
- Year
- 1990
- Tongue
- English
- Weight
- 315 KB
- Volume
- 1
- Category
- Article
- ISSN
- 1040-0400
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The r, structures of ethylene and 1,l-difluoroethylene have been determined by NMR of partially oriented molecules, considering the interaction between the solute molecule and the liquid crystal solvent which leads to a correlation between molecular vibration and rotation. The analysis of the data a
## Abstract It is demonstrated that in a case where neither the proton nor the natural‐abundance ^13^C‐satellite spectra of a partially oriented molecule carry enough structural information, one can determine the entire molecular geometry by the combined use of several liquid crystals as solvents.