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Determination of the rotational diffusion tensor for the sylvan molecule by13C nuclear magnetic relaxation

✍ Scribed by V. A. Daragan; A. Dias Ruano; I. V. Edneral

Book ID
112357564
Publisher
Springer
Year
1983
Tongue
English
Weight
415 KB
Volume
18
Category
Article
ISSN
0040-5760

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An investigation of rotational diffusion
An investigation of rotational diffusion of poly(Ξ³-benzyl-L-glutamate) in dilute solution by 13C nuclear magnetic relaxation
✍ C. Price; F. Heatley; T.J. Holton; P.A. Harris πŸ“‚ Article πŸ“… 1977 πŸ› Elsevier Science 🌐 English βš– 317 KB

13C spin-lattice relaxation times, TI, for the a-carbon nuclei of poly(r-benzyl-L%lutamate) fractions in deuterated DMF are shown to be governed by the diffusion coefficient for rotation about the helix axis, leading to an approximately linear dependence of TI on molecular weight. The p-l3 C spin-sp