๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Determination of the rotational diffusion by a picosecond phase fluorometer

โœ Scribed by H.-P. Haar; U.K.A. Klein; F.W. Hafner; M. Hauser

Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
374 KB
Volume
49
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

โœฆ Synopsis

The rotational diffusion of the o\ypyrenetrisulphonate .mion (OPS) in aqueous solution has been studied by measuring the time dependent fluorescence depolarization with .I phase fluorometer. In the temperature region from 10 to 95ยฐC the relaxation times vary between 136 and 26 ps. Comparison with the theory shows that the rotating volume IS ;1 sphere containing the OPS molecule and about 10 water molecules.

๐Ÿ“œ SIMILAR VOLUMES

Picosecond transient grating study of th
Picosecond transient grating study of the rotational diffusion of a ruthenium complex in solution
โœ Arthur Henseler; Eric Vauthey ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 697 KB

The rotational diffusion time of ruthenium( II)-bis( 2,2'-bipyridine) (2,2'-biquinoleine) has been measured in polar solvents of different viscosity. The rotational dynamics can be explained in terms of the Stokes-Einstein-Debye hydrodynamics theory under stick boundary condition by considering the

Determination of the diffusivity in elas
Determination of the diffusivity in elastomer solutions by batch sorption studies from a dilute liquid phase
โœ Gerard van Zee; Jan De Graauw ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 174 KB ๐Ÿ‘ 2 views

A simple batch sorption method is examined for diffusivity determinations of binary solutions of low molecular weight organic compounds in amorphous polymers. The method is based on solute uptake from a stirred liquid solution by a polymer sheet sample submerged in the liquid solution and measuremen