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Determination of the reaction enthalpy and kinetic parameters for the isomerization of bridged Dewar benzenes to 8,9-disubstituted [6]paracyclophanes by differential scanning calorimetry

✍ Scribed by Herbert Dreeskamp; Stefan M. Sarge; Werner Tochtermann

Publisher: Elsevier Science
Year: 1995
Tongue: French
Weight: 194 KB
Volume: 51
Category: Article
ISSN: 0040-4020
DOI: 10.1016/0040-4020(95)00072-g

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The kinetic parameters of the complex reaction between phenol and formaldehyde in the presence of sodium hydroxide (NaOH) have been obtained by differential scanning calorimetry (DSC). The two dominant reactions appear to be addition of formaldehyde to phenol with formation of o-hydroxymethyl-phenol