Determination of the rate constant of the reaction H+C2D4→ C2D3H+D
✍ Scribed by Yu. P. Yampol'skii
- Book ID
- 112437076
- Publisher
- Springer
- Year
- 1974
- Tongue
- English
- Weight
- 287 KB
- Volume
- 23
- Category
- Article
- ISSN
- 1573-9171
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Kinetic energy releases from the unimolecular 1~2 CD,) elimirzxtion reactions of energy-selected x 'Bag CzHz <CzDz) I~JW been obtsincd by a photoelectron-photoion coincidence technique\_ The energ\-releases susgest a 1.1 elimination and 3~ compatible xrith the presence of a small reverse activation
## Abstract The reactions of H/D with C~2~H~6~ and C~3~H~8~ have been studied with both shock‐tube experiments and ab initio transition‐state theory calculations. Rate constants for the reactions of D with C~2~H~6~ and C~3~H~8~ have been measured in reflected shock wave experiments over the tempera